See, this is one of the reasons why I prefer a center over private daycare.
You need to put a procedure in place that spells out your discipline options. You are a paid employee here. Neither you, nor your kids are served by just letting this go and really, it doesn't help the two boys you are watching either. Kids need boundaries and discipline to feel safe and be happy.
Sit down together with this mom and discuss what you have observed. Find a way together of disciplining the kids that you are both comfortable with.
When you first introduce time out (sitting in a corner), especially when you have not be consistent before, it will take a while for them to know that you mean business.
If he doesn't stay in his spot, place him back, again and again, restarting the timer. At first he'll think it's funny... but after a while it loses it's appeal and he will probably throw a tantrum. Normal. Just stick with it until he has actually spent the time he was supposed to in his spot.
I am not going to lie, it's going to be stressful for you too! Just remain calm and put him back.
In the meanwhile if you can and need to occupy the other kids, give them something to do that they love and maybe even that they don't get to do a lot. Ideally a somewhat quiet activity that doesn't require a lot of supervision, so you can give your attention to the offender.
Remember that discipline is not about punishment, it is about learning to control yourself as to not hurt others. I would never want for anyone to punich my daughter, but I do not mind close friends and her teachers disciplining her appropriately.
It will be harder know, because you have been inconsistent and let them run wild - but if you stick to whatever plan you come up with and give appropriate, immediate reactions to unwanted behavior - as well as praising good behavior, you will find your house becoming a whole lot calmer!
Good luck!