Hello A.!
I know it can be difficult to want to remain a supportive and loving sibling without getting caught up in the guilt. I have had a similar situation with my brother and his family. For me, it came down to choices. I truly believe that people make their own choices. Some learn from the bad or ill choices they have made and others do not. If your siblings are have continued to make bad decisions with your generosity, than I would say that you might need to try a different approach.
If they are complaining about a job situation or how they cannot make ends meet, offer websites, advice, etc. where they could find coupons, a new job search website or help re-write their resume. Try to offer suggestions or help that does not deal with money or inconvenience the relationship that you have with your husband or that jeopardizes what you might want for your family. Do not feel guilty for the good choices that you and your husband have made, especially now with a little girl to think about. If your siblings are not gracious with your new offers, than remember that it is their choices, not yours, that are making them feel that way.
Also, you have to ask yourself, what would they do for you given the tables were turned? Would they offer anything? I know it can be hard to think they wouldn't repay the favor and I hope you never the in the position to find out. However, when a hardship comes into your life, you really know who your true friends and family are.
I hope this has helped a little bit. I know that the guilt can be difficult, but if you can think about it and the scheme of choices and that they are responsible for their own, then I think that it will help.
Good Luck & if you need any additional advice or support, let me know.
K. O