S.B.
You might check with your local church to see if they would make a room available for free or for low cost. They probably would if this was presented as a public service, more so then as a profit making service. So you might teach an introductory class free and then let those that are interested, sign up for follow up classes.
I do like your idea of a networking seminar for moms with home-based businesses. I know several crafty moms who combine efforts and hold two craft fairs a year to sell their crafts. You could also do an on-line newsletter to promote each others businesses.